Product ID:NEUTRALIZING SOLUTION, N0898
MSDS Date:07/01/1999
FSC:6505
NIIN:00N092661
Status Code:A
MSDS Number: CJVMH

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

Telephone: 314-771-5765

Cage: 21076

(ORAL, RAT) 3310 MG/KG

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 25 MG/M3;10 PPM

ACGIH TLV: 25 MG/M3;10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENT AND TOXICOLOGICAL INFO
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: HARMFUL IF ABSORBED
THROUGH SKIN. MAY BE HARMFUL IF SWALLOWED. MAY BE HARMFUL IF
INHALED. VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES
AND UPPER RESPIRATORY TRACT. CAUSES S KIN IRRITATION. TARGET
ORGANS: TEETH, KIDNEYS. ALSO, SEE TOXICOLOGICAL INFORMATION.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: IN CASE OF CONTACT,
IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER.
INHALATI ON: IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON
IS CONSCIO US. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE
REUSE.

Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. COVER WITH
DRY LIME OR SODA ASH, PICK UP, KEEP IN A CLOSED CONTAINER AND HOLD
FOR WASTE DISPOSAL. VENTILA TE AREA AND WASH SPILL SITE AFTER
MATERIAL PICK UP IS COMPLETE.

Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL,
DRY PLACE.
Other Precautions:DO NOT BREATHE VAPOR. AVOID CONTACT WITH EYES, SKIN
AND CLOTHING. WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Supplemental Safety and Health
INGREDIENT INFORMATION: EC NO: 200-580-7.

Appearance and Odor:LIQUID.

ACIDS, BASES, OXIDIZING AGENTS, SOLUBLE CARBONATES AND PHOSPHATES,
HYDROXIDES, OXIDES, SULFUR, ACID ANHYDRIDES, PEROXIDES,
PERMANGANATES, AMINES, ALCOHOLS.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Toxicological Information:RTECS #: AF1225000. ACETIC ACID. IRRITATION
DATA: SKN-HMN 50 MG/24H MLD TXAPA9 31,481,1975. SKN-RBT 525 GM OPEN
SEV UCDS 8/7/1963. SKN-RBT 50 MG/24H MLD TXAPA9 31,481,1975.
EYE-RBT 5 MG/30S RINSE MLD TXCYAC 23,281,1982. TOXICITY DATA:
UNR-MAN LDLO: 308 MG/KG 85DCAI 2,73,1970. ORL-RAT LD50: 3310 MG/KG
DMDJAP 31,276,1959. IHL-MUS LC50:5620 PPM/1H MELAAD 48,559,1957.
IVN-MUS LD50: 525 MG/KG APTOA6 18 ,141,1961. SKN-RBT LD50: 1060
UL/KG UCDS 8/7/1963. TARGET ORGAN DATA: SENSE ORGANS & SPECIAL
SENSES (OTHER OLFACTION EFFECTS). SENSE ORGANS & SPECIAL SENSES
(OTHER EYE EFFECTS). BEHAVIORAL (CONVULSION S OR EFFECT ON
(ECOLOGICAL INFO)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE. --TOXICOLOGICAL INFO: SEIZURE
THRESHOLD). LUNGS, THORAX OR RESPIRATION (OTHER CHANGES).
GASTROINTESTINAL (CHANGES IN STRUCTURE OR FUNCTION OF ESOPHAGUS).
GASTROINTESTINAL (ULCE RATION OR BLEEDING FROM SMALL INTESTINE).
GASTROINTESTINAL (ULCERATION OR BLEEDING FROM LARGE INTESTINE).
EFFECTS ON FERTILITY (MALE FERTILITY INDEX). EFFECTS ON NEWBORN
(BEHAVIORAL). ONLY SELECTED RE GISTRY OF TOXIC EFFECTS OF CHEMICAL
SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN
RETECS FOR COMPLETE INFORMATION.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION. --FED REG INFO: (CONSTRUC): 8H TWA 10 PPM (25 MG/M3)
CFRGBR 29,1926.55,1994. OSHA PEL (SHIPYARD): 8H TWA 10 PPM (25
MG/M3) CFRGBR 29,1915 .1000,1993. OSHA PEL (FED CONT): 8H TWA 10
PPM (25 MG/M3) CFRGBR 41,50-204.50,1994. OEL-AUSTRALIA: TWA 10 PPM
(25 MG/M3); STEL 15 PPM (37 MG/M3) JAN 1993. OEL-AUSTRIA: TWA 10
PPM (25 MG/M3) JAN 1993. OEL-BELGIUM: TWA 10 PPM (25 MG/M3); STEL
15 PPM (37 MG/M3) JAN 1993. OEL-DENMARK: TWA 10 PPM (25 MG/M3) JAN
1993. OEL-FINLAND: TWA 10 PPM (25 MG/M3); STEL 15 PPM (37 MG/M3);
SKIN JAN 1993. OEL-FRANCE: STEL 10 PPM (25 MG/M3)(SARA REG INFO)

SARA Title III Information:N/P. TRANSPORT INFO: JAN 1993. OEL-GERMANY:
TWA 10 PPM (25 MG/M3) JAN 1993. OEL-HUNGARY: TWA 10 MG/M3; STEL 20
MG/M3 JAN 1993. OEL-INDIA: TWA 10 PPM (25 MG/M3); STEL 15 PPM (37
MG/M3) JAN 1993. OEL-JA PAN: TWA 10 PPM (25 MG/M3) JAN 1993.OEL-THE
NETHERLANDS: TWA 10 PPM (25 MG/M3) JAN 1993. OEL-THE PHILIPPINES:
TWA 10 PPM (25 MG/M3) JAN 1993. OEL-POLAND: TWA 5 MG/M3 JAN 1993.
OEL-RUSSIA: TWA 10 PPM; STEL 5 MG/M3: SKIN JAN 1993. OEL-SWEDEN:
TWA 10 PPM (25 MG/M3); STEL 15 PPM (35 MG/M3) JAN 1993.
OEL-SWITZERLAND: TWA 10 PPM (25 MG/M3); STEL 20 PPM (50 MG/M3) JAN
1993. OEL-THAILAND: TWA 10 PPM (25 M G/M3) JAN 1993. (STATE REG
INFO)
Federal Regulatory Information:EUROPEAN INFO - EC INDEX NO:
607-002-00-6. HARMFUL. R 36/38 IRRITATING TO EYES AND SKIN. S 26 IN
CASE OF CONTACT WTIH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER
AND SEEK MEDICAL ADVICE. S 36 WEAR SU ITABLE PROTECTIVE CLOTHING.
REVIEWS, STANDARDS AND REGULATIONS: OEL=MAK. ACGIH TLV-STEL 37
MG/M3 (15 PPM) DTLVS TLV/BEI, 1997. ACGIH TLV-TWA 25 MG/M3 (10 PPM)
DTLVS TLV/BEI,1977. EPA FIFRA 1988 PESTIC IDE SUBJECT TO
REGISTRATION OR RE-REGISTRATION FEREAC 54,7740,1989. MSHA
STANDARD-AIR: TWA 10 PPM (2 5 MG/M3) DTLVS 3,2,1971. OSHA PEL (GEN
INDU): 8H TWA 10 PPM (25 MG/M3) CFRGBR 29,1910.1000,1994. OSHA PEL
(CONSTRUC): (TRANSPORT INFO)
State Regulatory Information:N/P. SARA REG INFO: OEL-TURKEY: TWA 10 PPM
(25 MG/M3) JAN 1993. OEL-UNITED KINGDOM: TWA 10 PPM (25 MG/M3);
STEL 15 PPM (35 MG/M3) JAN 1993. OEL IN BULGARIA, COLOMBIA, JORDAN,
KOREA CHECK ACGIH TLV. OE L IN NEW ZEALAND, SINGAPORT, VIETNAM
CHECK ACGIH TLV. NIOSH REL TO ACETIC ACID-AIR: 10H TWA 10 PPM; STEL
15 PPM NIOSH DHHS #92-100,1992. NOHS 1974:HZD 01568; NIS 264; TNF
51469; NOS 150; TNE 486503. N OES 1983:HZD 01568; NIS 266; TNF
49403; NOS 169; TNE 907205; TFE 322123. EPA GENETOX PROGRAM 1988, N
EG: HISTIDINE REVERSION-AMES TEST. EPA TSCA SECTION 8(B) CHEM
INVENTORY. EPA TSCA SECTION 8(D) UNPUBLISHED HEALTH/SAFETY (OTHER
INFO)